If you're a company and wish to use Wise, you need to create an Enterprise account. When doing so, not every country is listed in the dropdown. I've personally been waiting for Brazil to be added for almost 2 years at this point. It's a great service that would help me out a lot.
As far as I know it is simply not allowed to make any sort of business-related transaction on a personal account, regardless of the size of your business or anything else. I asked them if that was a possibility when I saw it wasn't possible to open a Business account for a brazilian company, and they very clearly said no.
I received $50 last year through Payoneer for a quick freelancing job and completely forgot about it.
A year later, last week, I remembered and decided to withdraw it only to find out that I was deducted $30 for not using the account. Shitty, but I decided to just withdraw the rest and be done with it, only to be faced with the fact that they have a minimum withdraw amount.
I then proceeded to send them an e-mail requesting immediate termination of my account as they literally stole money from my account. I do not recommend this service to anyone.