Lagrange orbits aren't that great in the long run, and come with their own unique set of challenges (from en.wikipedia.org/wiki/Lagrangian_point#Mathematical_details):
"Although the L1, L2, and L3 points are nominally unstable, it turns out that it is possible to find (unstable) periodic orbits around these points, at least in the restricted three-body problem. These periodic orbits, referred to as "halo" orbits, do not exist in a full n-body dynamical system such as the Solar System. However, quasi-periodic (i.e. bounded but not precisely repeating) orbits following Lissajous-curve trajectories do exist in the n-body system. These quasi-periodic Lissajous orbits are what most of Lagrangian-point missions to date have used. Although they are not perfectly stable, a relatively modest effort at station keeping can allow a spacecraft to stay in a desired Lissajous orbit for an extended period of time. It also turns out that, at least in the case of Sun–Earth-L1 missions, it is actually preferable to place the spacecraft in a large-amplitude (100,000–200,000 km or 62,000–124,000 mi) Lissajous orbit, instead of having it sit at the Lagrangian point, because this keeps the spacecraft off the direct line between Sun and Earth, thereby reducing the impact of solar interference on Earth–spacecraft communications. Similarly, a large-amplitude Lissajous orbit around L2 can keep a probe out of Earth's shadow and therefore ensures a better illumination of its solar panels."
Earth-Moon L4 and L5 is still very unstable due to the Sun (and other planets).
Earth-Sun L4 and L5 is more stable, but almost useless as a waypoint; however there are already naturally captured asteroids (and a lot of dust) already there.
All orbits require station keeping in a dynamic solar system that is circling around a black hole.
If the asteroid has any water, station keeping won't require external fuel. If it doesn't, mass drivers could be used to toss chunks of the asteroid off and correct for instability (though that might create space debris if the velocity isn't enough).
"Although the L1, L2, and L3 points are nominally unstable, it turns out that it is possible to find (unstable) periodic orbits around these points, at least in the restricted three-body problem. These periodic orbits, referred to as "halo" orbits, do not exist in a full n-body dynamical system such as the Solar System. However, quasi-periodic (i.e. bounded but not precisely repeating) orbits following Lissajous-curve trajectories do exist in the n-body system. These quasi-periodic Lissajous orbits are what most of Lagrangian-point missions to date have used. Although they are not perfectly stable, a relatively modest effort at station keeping can allow a spacecraft to stay in a desired Lissajous orbit for an extended period of time. It also turns out that, at least in the case of Sun–Earth-L1 missions, it is actually preferable to place the spacecraft in a large-amplitude (100,000–200,000 km or 62,000–124,000 mi) Lissajous orbit, instead of having it sit at the Lagrangian point, because this keeps the spacecraft off the direct line between Sun and Earth, thereby reducing the impact of solar interference on Earth–spacecraft communications. Similarly, a large-amplitude Lissajous orbit around L2 can keep a probe out of Earth's shadow and therefore ensures a better illumination of its solar panels."